Poly[1,4-bis(ammoniomethyl)cyclohexane [di-μ-bromido-dibromidoplumbate(II)]]
نویسندگان
چکیده
The title compound, {(C(8)H(20)N(2))[PbBr(4)]}(n), crystallizes as an inorganic-organic hybrid with alternating layers of diammonium cations and two-dimensional corner-sharing PbBr(6) octa-hedra extending parallel to the bc plane, which are eclipsed relative to one another. Both PbBr(6) octa-hedra and the organic cation exhibit symmetry. The cations inter-act via N-H⋯Br hydrogen bonding in the right-angled halogen sub-type of the terminal halide hydrogen-bonding motif.
منابع مشابه
Poly[1,4-bis(ammoniomethyl)cyclohexane [di-μ-iodido-diiodidoplumbate(II)]]
The title compound, {(C(8)H(20)N(2))[PbI(4)]}(n), is an inorganic-organic hybrid. The structure is composed of alternate layers of two-dimensional corner-sharing PbI(6) octa-hedra ( symmetry) and 1,4-bis-(ammonio-meth-yl)cyclo-hexane cations ( symmetry) extending parallel to the bc plane. The cations inter-act with the inorganic layer via N-H⋯I hydrogen bonding in the right-angled halogen sub-t...
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